Search results for "Chiral separation"

showing 2 items of 2 documents

Direct chromatographic study of the enantioselective biodegradation of ibuprofen and ketoprofen by an activated sludge

2018

[EN] The quantification of the enantiomeric fraction (EF) during the biodegradation process is essential for environmental risk assessment. In this paper the enantioselective biodegradation of ibuprofen, IBU, and ketoprofen, KET, two of the drugs most consumed, was evaluated. Biodegradation experiments were performed in batch mode using a minimal salts medium inoculated with an activated sludge (collected from a Valencian Waste Water Treatment Plant) and supplemented with the racemate of each compound. The inoculum activity was verified using fluoxetine as reference compound. The experimental conditions used (analyte concentration and volume of inoculum) were chosen according to OECD guidel…

KetoprofenAnalyteCalibration curveIbuprofenFraction (chemistry)Wastewater010501 environmental sciences01 natural sciencesBiochemistryAnalytical ChemistryPeak area based estimatesEnantioselective biodegradationmedicineChromatography High Pressure Liquid0105 earth and related environmental sciencesChromatographySewageChemistryBatch experiment010401 analytical chemistryOrganic ChemistryStereoisomerismGeneral MedicineBiodegradationIbuprofenChiral separation0104 chemical sciencesKineticsBiodegradation EnvironmentalActivated sludgeKetoprofenCalibrationEnantiomermedicine.drugJournal of Chromatography A
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Application of molecularly imprinted polymers in analytical chiral separations and analysis

2018

Over the last two decades the process of development and application of a new types of molecular imprinted polymer (MIP) sorbents in the field of analytical chemistry have been widely described in the literature. One of the new trends in analytical chemistry practice is the use of new types of MIP sorbents as specific sorption materials constituting the stationary phase in advanced separation techniques. The following review paper contains comprehensive information about the application of a specific and well defined MIP sorbents (with the data base in the paper about the reagents used in MIP preparation process) as stationary phases in separation techniques including high performance liqui…

Capillary electrochromatographychiral separationMaterials sciencehigh performance liquid chromatography010401 analytical chemistryMolecularly imprinted polymerEnantioselective synthesisNanotechnologySorptionenantiomers02 engineering and technologycapillary electrochromatography021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesAnalytical ChemistryStationary phasemolecularly imprinted polymers0210 nano-technologySpectroscopyTrac-Trends in Analytical Chemistry
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